Well, this is a very interesting question, Wade. I guess this would be my favorite order:
1) Review Moderator - I would like to be a review mod most of all because I spend most of my valuable time here on newgrounds reviewing, and I have a pretty nice whistle level to bat. And to add to that I am most familiar with reviewing than anything, I know the rules of reviewing front to back.
2) Forum Moderator - I guess I would like to be a forum mod second because if I'm not looking out for bad reviews, I'm lurking around the BBS and posting. And it also irritates me a lot to see stupid threads that you see over and over and not being able to do anything to get rid of it other than contacting a mod.
Well, those two are the only to moderation positions that I admit I would actually be use to and good at, I hope this helps.
~Sectus