I wrote the main riff intending to use it for a more complex rock instrumental. Actually it was going to be a theme song for an animation project that hopefully someday will come into existence. While tinkering with guitar effects, I found a Blues setting on my effects board and decided that I could capture the tune of the theme in a really cool way and decided to make it into a guitar duo. There are only two places where more than two guitars are layered, and the drums at the end just went into to give it closure.
Please contact me if you would like to use this in a project. We can discuss the details.