Maybe she accidentally behaved in a way that you subconsciously desire in women. This could be a lot of things, and I can only project based on my own experience. How old are you and how experienced are you with the opposite sex? There is such a thing called "limerence," which is when someone is so overwhelmingly and illogically attracted to the opposite sex. It's most prevalent in teenagers who have a naíve and inexperienced view on love, and typically lasts about 18 months.
It's hard to say honestly. The tongue by itself as the reason for arousal is sexual, but there could be more to it. Maybe thw tongue hanging out magnified certain aspects of her personality that you already know and something 'clicked.'